Information card for entry 7700600

Structure parameters

• Formula: C51 H40 Cl2 N2 O P2 Rh2
• Calculated formula: C51 H40 Cl2 N2 O P2 Rh2
• Title of publication: Rh(i) and Ru(ii) phosphaamidine and phosphaguanidine (1,3-P,N) complexes and their activity for CO₂ hydrogenation.
• Authors of publication: Kandel, Ramjee; Schatte, Gabriele; Jessop, Philip G.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 33
• Pages of publication: 12512 - 12521
• a: 19.2924 ± 0.0004 Å
• b: 18.355 ± 0.0004 Å
• c: 16.0363 ± 0.0004 Å
• α: 90°
• β: 102.593 ± 0.001°
• γ: 90°
• Cell volume: 5542 ± 0.2 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.055
• Residual factor for significantly intense reflections: 0.0366
• Weighted residual factors for significantly intense reflections: 0.0852
• Weighted residual factors for all reflections included in the refinement: 0.0926
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No