Information card for entry 7700753

Structure parameters

• Common name: [TlMe2(N3Dmp2)]
• Formula: C50 H56 N3 Tl
• Calculated formula: C50 H56 N3 Tl
• Title of publication: Kinetic stabilization of low-oxidation state and terminal hydrido main group metal complexes by a sterically demanding N,N'-bis(2,6-terphenyl)triazenide.
• Authors of publication: Leverett, Anthony R.; Diachenko, Vera; Cole, Marcus L.; McKay, Alasdair I.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 35
• Pages of publication: 13197 - 13204
• a: 10.5327 ± 0.0008 Å
• b: 15.702 ± 0.0012 Å
• c: 51.888 ± 0.004 Å
• α: 90°
• β: 93.222 ± 0.003°
• γ: 90°
• Cell volume: 8567.9 ± 1.1 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150.15 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0995
• Residual factor for significantly intense reflections: 0.0551
• Weighted residual factors for significantly intense reflections: 0.1091
• Weighted residual factors for all reflections included in the refinement: 0.1227
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No