Information card for entry 7702195

Structure parameters

• Common name: Dinuclear cobalt(II) complex of rearranged ligand
• Formula: C32 H32 B4 Br4 Co2 F12 N8 O4
• Calculated formula: C32 H32 B4 Br4 Co2 F12 N8 O4
• Title of publication: Substituents drive ligand rearrangements, giving dinuclear rather than mononuclear complexes, and tune Co^II/III redox potential.
• Authors of publication: Karabulut, Fabrice N. H.; Feltham, Humphrey L. C.; Brooker, Sally
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 34
• Pages of publication: 11749 - 11759
• a: 15.3342 ± 0.0003 Å
• b: 17.0365 ± 0.0003 Å
• c: 20.3884 ± 0.0004 Å
• α: 90°
• β: 111.213 ± 0.002°
• γ: 90°
• Cell volume: 4965.39 ± 0.18 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 15
• Hermann-Mauguin space group symbol: I 1 2/c 1
• Hall space group symbol: -I 2yc
• Residual factor for all reflections: 0.0738
• Residual factor for significantly intense reflections: 0.0728
• Weighted residual factors for significantly intense reflections: 0.1927
• Weighted residual factors for all reflections included in the refinement: 0.1933
• Goodness-of-fit parameter for all reflections included in the refinement: 1.135
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No