Information card for entry 7702658

Structure parameters

• Formula: C41 H51 F6 O2 P2 Rh
• Calculated formula: C41 H53 F6 O2 P2 Rh
• Title of publication: Novel single or double insertion of alkynes into rhodium‒ and iridium‒oxygen or ‒phosphorus atom bonds and transannular addition of 1-alkynes between the rhodium atom and the ipso-carbon atom of the phosphorus ligand
• Authors of publication: Yamamoto, Yasuhiro; Sugawara, Kenichiro; Han, Xiao-Hong
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 2
• Pages of publication: 195
• a: 11.575 ± 0.004 Å
• b: 16.67 ± 0.01 Å
• c: 10.8 ± 0.005 Å
• α: 90.17 ± 0.05°
• β: 99.46 ± 0.03°
• γ: 93.41 ± 0.04°
• Cell volume: 2051.8 ± 1.7 ų
• Cell temperature: 299.2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0716
• Weighted residual factors for all reflections included in the refinement: 0.0754
• Goodness-of-fit parameter for all reflections included in the refinement: 1.283
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No