Information card for entry 7702933

Structure parameters

• Formula: C25 H39 Cl2 O P Ru
• Calculated formula: C25 H39 Cl2 O P Ru
• Title of publication: Half-sandwich ruthenium(ii) complexes with tethered arene-phosphinite ligands: synthesis, structure and application in catalytic cross dehydrogenative coupling reactions of silanes and alcohols.
• Authors of publication: González-Fernández, Rebeca; Crochet, Pascale; Cadierno, Victorio
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 1
• Pages of publication: 210 - 222
• a: 9.3696 ± 0.0001 Å
• b: 15.1236 ± 0.0002 Å
• c: 18.3093 ± 0.0002 Å
• α: 90°
• β: 98.796 ± 0.001°
• γ: 90°
• Cell volume: 2563.95 ± 0.05 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0253
• Residual factor for significantly intense reflections: 0.0216
• Weighted residual factors for significantly intense reflections: 0.0508
• Weighted residual factors for all reflections included in the refinement: 0.0528
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No