Information card for entry 7703898

Structure parameters

• Chemical name: [(Piso)Rh(CO)2]
• Formula: C31 H43 N2 O2 Rh
• Calculated formula: C31 H43 N2 O2 Rh
• SMILES: [Rh]1([N](=C(C(C)(C)C)N1c1c(cccc1C(C)C)C(C)C)c1c(cccc1C(C)C)C(C)C)(C#[O])C#[O]
• Title of publication: Bulky bis(aryl)triazenides: just aspiring amidinates? A structural and spectroscopic study.
• Authors of publication: Gyton, Matthew R.; Leverett, Anthony R.; Cole, Marcus L.; McKay, Alasdair I.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 17
• Pages of publication: 5653 - 5661
• a: 10.2807 ± 0.0004 Å
• b: 10.9865 ± 0.0004 Å
• c: 14.6713 ± 0.0005 Å
• α: 70.88 ± 0.0011°
• β: 79.7465 ± 0.0013°
• γ: 74.6877 ± 0.0015°
• Cell volume: 1502.48 ± 0.1 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0265
• Residual factor for significantly intense reflections: 0.0242
• Weighted residual factors for significantly intense reflections: 0.0609
• Weighted residual factors for all reflections included in the refinement: 0.0625
• Goodness-of-fit parameter for all reflections included in the refinement: 1.055
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No