Information card for entry 7704537

Structure parameters

• Formula: C32 H54 Cl2 N3 O P Pd Si
• Calculated formula: C32 H54 Cl2 N3 O P Pd Si
• SMILES: CC(C)(C)[N]1=C(c2ccccc2)N(C(C)(C)C)[Si]21n1cccc1C[P](C(C)(C)C)(C(C)(C)C)[Pd]2(Cl)Cl.C1CCCO1
• Title of publication: Phosphane-functionalized heavier tetrylenes: synthesis of silylene- and germylene-decorated phosphanes and their reactions with Group 10 metal complexes.
• Authors of publication: Cabeza, Javier A.; García-Álvarez, Pablo; Laglera-Gándara, Carlos J; Pérez-Carreño, Enrique
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 24
• Pages of publication: 8331 - 8339
• a: 18.2783 ± 0.0004 Å
• b: 10.5426 ± 0.0002 Å
• c: 18.3984 ± 0.0004 Å
• α: 90°
• β: 94.109 ± 0.002°
• γ: 90°
• Cell volume: 3536.27 ± 0.13 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0467
• Residual factor for significantly intense reflections: 0.0432
• Weighted residual factors for significantly intense reflections: 0.1187
• Weighted residual factors for all reflections included in the refinement: 0.1209
• Goodness-of-fit parameter for all reflections included in the refinement: 1.079
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No