Information card for entry 7704635

Structure parameters

• Common name: (^H^ap)2Os(OCH2CH2O) . 0.5 C6H14
• Chemical name: Bis(2-phenylimido-4,6-di-tert-butylphenoxo)ethyleneglycolato-osmium(VI) hemi-hexane solvate
• Formula: C45 H61 N2 O4 Os
• Calculated formula: C45 H61 N2 O4 Os
• Title of publication: High-valent osmium iminoxolene complexes.
• Authors of publication: Gianino, Jacqueline; Erickson, Alexander N.; Markovitz, Sean J.; Brown, Seth N.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 25
• Pages of publication: 8504 - 8515
• a: 12.2153 ± 0.0006 Å
• b: 13.1499 ± 0.0007 Å
• c: 13.2104 ± 0.0007 Å
• α: 103.123 ± 0.0017°
• β: 91.7443 ± 0.0016°
• γ: 97.8182 ± 0.0017°
• Cell volume: 2043.22 ± 0.18 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0438
• Residual factor for significantly intense reflections: 0.0357
• Weighted residual factors for significantly intense reflections: 0.0672
• Weighted residual factors for all reflections included in the refinement: 0.0692
• Goodness-of-fit parameter for all reflections included in the refinement: 1.121
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No