Information card for entry 7704751

Structure parameters

• Formula: C47 H39 As Au Cl5 N2 O2 P2 Ru
• Calculated formula: C46 H38 As Au Cl2 N2 O2 P2 Ru
• SMILES: [Au]([As]12[Ru](Cl)([P](c3ccccc3)(c3ccccc3)c3ccccc3)([P](c3ccccc3)(c3ccccc3)c3ccccc3)([n]3c(O1)cccc3)[n]1c(O2)cccc1)Cl
• Title of publication: (2-Pyridyloxy)arsines as ligands in transition metal chemistry: a stepwise As(iii) →As(ii) →As(i) reduction.
• Authors of publication: Gericke, Robert; Wagler, Jörg
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 29
• Pages of publication: 10042 - 10051
• a: 12.3889 ± 0.0006 Å
• b: 12.8306 ± 0.0006 Å
• c: 15.0564 ± 0.0007 Å
• α: 97.133 ± 0.004°
• β: 102.51 ± 0.004°
• γ: 94.659 ± 0.004°
• Cell volume: 2303.93 ± 0.19 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0458
• Residual factor for significantly intense reflections: 0.0333
• Weighted residual factors for significantly intense reflections: 0.0789
• Weighted residual factors for all reflections included in the refinement: 0.0854
• Goodness-of-fit parameter for all reflections included in the refinement: 1.065
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No