Information card for entry 7705320

Structure parameters

• Formula: C26 H54 N2 Si5
• Calculated formula: C26 H54 N2 Si5
• SMILES: [Si]([Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)(C1(C(=C(C(=C1C)C)C)C)C)=C1N(C(=C(N1C)C)C)C
• Title of publication: Pentamethylcyclopentadienyl-substituted hypersilylsilylene: reversible and irreversible activation of C[double bond, length as m-dash]C double bonds and dihydrogen.
• Authors of publication: Leszczyńska, Kinga I; Deglmann, Peter; Präsang, Carsten; Huch, Volker; Zimmer, Michael; Schweinfurth, David; Scheschkewitz, David
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 38
• Pages of publication: 13218 - 13225
• a: 40.367 ± 0.013 Å
• b: 9.976 ± 0.003 Å
• c: 16.657 ± 0.005 Å
• α: 90°
• β: 99.403 ± 0.019°
• γ: 90°
• Cell volume: 6618 ± 4 ų
• Cell temperature: 142 ± 2 K
• Ambient diffraction temperature: 142 ± 2 K
• Number of distinct elements: 4
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0505
• Residual factor for significantly intense reflections: 0.0329
• Weighted residual factors for significantly intense reflections: 0.0829
• Weighted residual factors for all reflections included in the refinement: 0.092
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No