Information card for entry 7706353

Structure parameters

• Formula: P4 Rb4 S14 Sm2
• Calculated formula: P4 Rb4 S14 Sm2
• Title of publication: A series of Rb₄Ln₂(P₂S₆)(PS₄)₂ (Ln = La, Ce, Pr, Nd, Sm, Gd) rare earth thiophosphates with two distinct thiophosphate units [P^VS₄]^3- and [P^IV₂S₆]⁴.
• Authors of publication: Kutahyali Aslani, Ceren; Breton, Logan S.; Klepov, Vladislav V.; Zur Loye, Hans-Conrad
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2021
• Journal volume: 50
• Journal issue: 5
• Pages of publication: 1683 - 1689
• a: 22.8828 ± 0.0005 Å
• b: 6.8072 ± 0.0001 Å
• c: 18.8375 ± 0.0004 Å
• α: 90°
• β: 121.912 ± 0.001°
• γ: 90°
• Cell volume: 2490.79 ± 0.09 ų
• Cell temperature: 303 ± 2 K
• Ambient diffraction temperature: 302.72 K
• Number of distinct elements: 4
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0278
• Residual factor for significantly intense reflections: 0.0227
• Weighted residual factors for significantly intense reflections: 0.0462
• Weighted residual factors for all reflections included in the refinement: 0.0481
• Goodness-of-fit parameter for all reflections included in the refinement: 1.103
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No