Information card for entry 7706855

Structure parameters

• Common name: Rh(acac)CO(o-fluoro-9-phosphatriptycene complex)
• Chemical name: (acetylacetonato)-carbonylrhodium-ortho-fluoro-9-phosphatriptycene complex
• Formula: C25 H19 F O3 P Rh
• Calculated formula: C25 H19 F O3 P Rh
• Title of publication: Sterically hindered ortho-substituted phosphatriptycenes as configurationally stable P-chirogenic triarylphosphines.
• Authors of publication: Hu, Lei; Mahaut, Damien; Tumanov, Nikolay; Wouters, Johan; Collard, Laurent; Robiette, Raphaël; Berionni, Guillaume
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2021
• Journal volume: 50
• Journal issue: 14
• Pages of publication: 4772 - 4777
• a: 9.5012 ± 0.0002 Å
• b: 15.7667 ± 0.0005 Å
• c: 16.69 ± 0.0005 Å
• α: 65.119 ± 0.003°
• β: 80.211 ± 0.002°
• γ: 75.563 ± 0.002°
• Cell volume: 2190.48 ± 0.12 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 295 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0445
• Residual factor for significantly intense reflections: 0.0349
• Weighted residual factors for significantly intense reflections: 0.0943
• Weighted residual factors for all reflections included in the refinement: 0.102
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No