Information card for entry 7706859

Structure parameters

• Common name: Rh(acac)CO(o-chloro-9-phosphatriptycene complex)
• Chemical name: (acetylacetonato)-carbonylrhodium-ortho-chloro-9-phosphatriptycene complex
• Formula: C25 H19 Cl O3 P Rh
• Calculated formula: C25 H19 Cl O3 P Rh
• Title of publication: Sterically hindered ortho-substituted phosphatriptycenes as configurationally stable P-chirogenic triarylphosphines.
• Authors of publication: Hu, Lei; Mahaut, Damien; Tumanov, Nikolay; Wouters, Johan; Collard, Laurent; Robiette, Raphaël; Berionni, Guillaume
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2021
• Journal volume: 50
• Journal issue: 14
• Pages of publication: 4772 - 4777
• a: 8.62702 ± 0.0001 Å
• b: 21.4229 ± 0.0002 Å
• c: 12.62171 ± 0.00015 Å
• α: 90°
• β: 107.165 ± 0.0013°
• γ: 90°
• Cell volume: 2228.78 ± 0.05 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 295 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0313
• Residual factor for significantly intense reflections: 0.0293
• Weighted residual factors for significantly intense reflections: 0.0723
• Weighted residual factors for all reflections included in the refinement: 0.0736
• Goodness-of-fit parameter for all reflections included in the refinement: 1.09
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No