Information card for entry 7707639

Structure parameters

• Formula: C30 H24 Au F6 N P Sb
• Calculated formula: C30 H24 Au F6 N P Sb
• SMILES: [Au]([P](c1ccccc1)(Cc1c2c3ccccc3c2ccc1)c1ccccc1)[n]1ccccc1.[Sb](F)(F)(F)(F)([F-])F
• Title of publication: Non-palindromic (C^C^D) gold(III) pincer complexes are not accessible by intramolecular oxidative addition of biphenylenes - an experimental and quantum chemical study.
• Authors of publication: Feuerstein, Wolfram; Breher, Frank
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2021
• Journal volume: 50
• Journal issue: 28
• Pages of publication: 9754 - 9767
• a: 16.301 ± 0.003 Å
• b: 17.737 ± 0.004 Å
• c: 20.159 ± 0.004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5829 ± 2 ų
• Cell temperature: 200 K
• Ambient diffraction temperature: 200 K
• Number of distinct elements: 7
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0446
• Residual factor for significantly intense reflections: 0.0389
• Weighted residual factors for significantly intense reflections: 0.101
• Weighted residual factors for all reflections included in the refinement: 0.1053
• Goodness-of-fit parameter for all reflections included in the refinement: 1.111
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No