Information card for entry 7708153

Structure parameters

• Formula: C14 H39 N7 O3 P2
• Calculated formula: C14 H39 N7 O3 P2
• SMILES: P(N(C)C)(N(C)C)(N(C)C)=N[P+](N(C)C)(N(C)C)N(C)C.[O-]C(=O)OC
• Title of publication: Heavy silylchalcogenido lanthanates synthesis Ph₄P[Cp₃La-ESiMe₃] (E = S, Se, and Te) <i>via</i> fluoride-induced demethylation of dimethylcarbonate to Ph₄P[OCO₂Me] key intermediate.
• Authors of publication: Guschlbauer, Jannick; Vollgraff, Tobias; Xie, Xiulan; Fetoh, Ahmed; Sundermeyer, Jörg
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2021
• Journal volume: 50
• Journal issue: 37
• Pages of publication: 13103 - 13111
• a: 7.9237 ± 0.0002 Å
• b: 11.4184 ± 0.0004 Å
• c: 12.7068 ± 0.0004 Å
• α: 103.005 ± 0.002°
• β: 98.958 ± 0.002°
• γ: 96.125 ± 0.002°
• Cell volume: 1094.44 ± 0.06 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0554
• Residual factor for significantly intense reflections: 0.0478
• Weighted residual factors for significantly intense reflections: 0.1314
• Weighted residual factors for all reflections included in the refinement: 0.1354
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No