Information card for entry 7708711

Structure parameters

• Chemical name: AS-370
• Formula: C44 H48 O14 P2 W2
• Calculated formula: C44 H48 O14 P2 W2
• Title of publication: A homonuclear π-system with a singlet carbene-type alpha and a nucleophilic beta phosphorus – first use in P-heterocyclic synthesis
• Authors of publication: Schmer, Alexander; Welideniya, Dhanushi; Terschüren, Tatjana; Schnakenburg, Gregor; Daniels, Jörg; Bauza, Antonio; Frontera, Antonio; Streubel, R.
• Journal of publication: Dalton Transactions
• Year of publication: 2021
• a: 9.838 ± 0.003 Å
• b: 12.198 ± 0.004 Å
• c: 21.758 ± 0.007 Å
• α: 89.481 ± 0.009°
• β: 80.738 ± 0.009°
• γ: 67.861 ± 0.009°
• Cell volume: 2383.2 ± 1.3 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1288
• Residual factor for significantly intense reflections: 0.0767
• Weighted residual factors for significantly intense reflections: 0.1664
• Weighted residual factors for all reflections included in the refinement: 0.1991
• Goodness-of-fit parameter for all reflections included in the refinement: 1.103
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No