Information card for entry 7709105

Structure parameters

• Chemical name: [{N(2,6-iPr-C6H3)}2(CMe)2CH]2Mg2(tBuCP)*hex
• Formula: C69 H105 Mg2 N4 P
• Calculated formula: C69 H105 Mg2 N4 P
• Title of publication: Reduction of tert-butylphosphaalkyne and trimethylsilylnitrile with magnesium(I) dimers
• Authors of publication: Wilson, Daniel; Jones, Dafydd; Smith, Cory; Mehta, Meera; Jones, Cameron; Goicoechea, Jose M.
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 21.8841 ± 0.0004 Å
• b: 11.3716 ± 0.0002 Å
• c: 29.3532 ± 0.0005 Å
• α: 90°
• β: 111.49 ± 0.002°
• γ: 90°
• Cell volume: 6796.9 ± 0.2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0518
• Residual factor for significantly intense reflections: 0.0418
• Weighted residual factors for significantly intense reflections: 0.1115
• Weighted residual factors for all reflections included in the refinement: 0.1201
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No