Information card for entry 7709109

Structure parameters

• Chemical name: [{N(2,4,6-Me-C6H2)}2(CMe)2CH]2Mg2(tBuCP)2(THF)
• Formula: C60 H84 Mg2 N4 O P2
• Calculated formula: C60 H84 Mg2 N4 O P2
• Title of publication: Reduction of tert-butylphosphaalkyne and trimethylsilylnitrile with magnesium(I) dimers
• Authors of publication: Wilson, Daniel; Jones, Dafydd; Smith, Cory; Mehta, Meera; Jones, Cameron; Goicoechea, Jose M.
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 11.6939 ± 0.0007 Å
• b: 14.1088 ± 0.0006 Å
• c: 19.711 ± 0.0008 Å
• α: 72.352 ± 0.004°
• β: 76.371 ± 0.004°
• γ: 73.373 ± 0.005°
• Cell volume: 2929.7 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0904
• Residual factor for significantly intense reflections: 0.065
• Weighted residual factors for significantly intense reflections: 0.1663
• Weighted residual factors for all reflections included in the refinement: 0.182
• Goodness-of-fit parameter for all reflections included in the refinement: 1.062
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No