Information card for entry 7709207

Structure parameters

• Chemical name: Complex of Cu(I) iodide with bis(2-pyridyl)phenylarsine
• Formula: C32 H26 As2 Cu2 I2 N4
• Calculated formula: C32 H26 As2 Cu2 I2 N4
• Title of publication: Pyridylarsine-based Cu(I) complexes showing TADF mixed with fast phosphorescence: a speeding-up emission rate using arsine ligands.
• Authors of publication: Artem'ev, Alexander V.; Demyanov, Yan V.; Rakhmanova, Marianna I.; Bagryanskaya, Irina Yu
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2021
• a: 9.0573 ± 0.0011 Å
• b: 9.1282 ± 0.001 Å
• c: 20.279 ± 0.003 Å
• α: 86.324 ± 0.004°
• β: 87.224 ± 0.005°
• γ: 87.348 ± 0.004°
• Cell volume: 1669.6 ± 0.4 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.055
• Residual factor for significantly intense reflections: 0.0434
• Weighted residual factors for significantly intense reflections: 0.1153
• Weighted residual factors for all reflections included in the refinement: 0.1242
• Goodness-of-fit parameter for all reflections included in the refinement: 0.715
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No