Information card for entry 7709293

Structure parameters

• Formula: C85 H109 Cl4 Ga2 N4 Si
• Calculated formula: C85 H109 Cl4 Ga2 N4 Si
• Title of publication: Geminal C-Cl and Si-Cl bond activation of chloromethanes and chlorosilanes by gallanediyl LGa.
• Authors of publication: Helling, Christoph; Ganesamoorthy, Chelladurai; Wölper, Christoph; Schulz, Stephan
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2022
• Journal volume: 51
• Journal issue: 5
• Pages of publication: 2050 - 2058
• a: 12.8721 ± 0.0012 Å
• b: 15.8286 ± 0.0015 Å
• c: 20.983 ± 0.002 Å
• α: 92.951 ± 0.005°
• β: 91.421 ± 0.005°
• γ: 109.252 ± 0.004°
• Cell volume: 4026.8 ± 0.7 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0442
• Residual factor for significantly intense reflections: 0.0319
• Weighted residual factors for significantly intense reflections: 0.0789
• Weighted residual factors for all reflections included in the refinement: 0.0892
• Goodness-of-fit parameter for all reflections included in the refinement: 1.069
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No