Information card for entry 7709336

Structure parameters

• Chemical name: Bis(triphenylsilyl)phosphanide sodium(18-crown-6)(1,2-dimethoxyethane)1/2 salt
• Formula: C50 H59 Na O7 P Si2
• Calculated formula: C50 H59 Na O7 P Si2
• Title of publication: Simple conversion of trisodium phosphide, Na3P, into silyl- and cyanophosphides and structure of a terminal silver phosphide
• Authors of publication: Grützmacher, Hansjörg; Le Corre, Grégoire
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 12.2084 ± 0.0003 Å
• b: 12.5732 ± 0.0004 Å
• c: 16.8295 ± 0.0005 Å
• α: 98.695 ± 0.002°
• β: 107.907 ± 0.002°
• γ: 101.613 ± 0.002°
• Cell volume: 2344.09 ± 0.13 ų
• Cell temperature: 100.01 ± 0.15 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0564
• Residual factor for significantly intense reflections: 0.0393
• Weighted residual factors for significantly intense reflections: 0.0861
• Weighted residual factors for all reflections included in the refinement: 0.0938
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No