Information card for entry 7709362

Structure parameters

• Formula: C24 H100 Co5 N16 O54 Si4 V16
• Calculated formula: C24 H72 Co5 N16 O49 Si4 V16
• Title of publication: Three Si-substituted polyoxovanadates as efficient catalysts for Knoevenagel condensation and selective oxidation of styrene to benzaldehyde.
• Authors of publication: Shi, Yu; Zhou, Tong; Di, Jia-Qi; Wang, Wenhui; Ma, Li; Zhang, Heng; Gao, Yuanzhe
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2022
• Journal volume: 51
• Journal issue: 8
• Pages of publication: 3304 - 3313
• a: 12.9632 ± 0.0009 Å
• b: 13.8288 ± 0.001 Å
• c: 14.4745 ± 0.0011 Å
• α: 91.784 ± 0.001°
• β: 98.765 ± 0.001°
• γ: 96.339 ± 0.001°
• Cell volume: 2545.8 ± 0.3 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0583
• Residual factor for significantly intense reflections: 0.0489
• Weighted residual factors for significantly intense reflections: 0.1393
• Weighted residual factors for all reflections included in the refinement: 0.1458
• Goodness-of-fit parameter for all reflections included in the refinement: 1.019
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No