Information card for entry 7709623

Structure parameters

• Chemical name: Bis(ammonium)[dodecakis(μ~2~-pentafluoropropionato)hexakis(pentafluoro- propionic acid)octa(μ~3~-fluorido)hexaeuropium(III)]-pentafluoropropionic acid (1/8)'
• Formula: C78 H22 Eu6 F138 N2 O52
• Calculated formula: C78 H22 Eu6 F138 N2 O52
• Title of publication: Oxidation of europium with ammonium perfluorocarboxylates in liquid ammonia: Pathways to europium(II) carboxylates and hexanuclear europium(III) fluoridocarboxylate complexes
• Authors of publication: Morsbach, Florian; Klenner, Steffen; Pöttgen, Rainer; Frank, Walter
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 17.6214 ± 0.0013 Å
• b: 33.28 ± 0.002 Å
• c: 26.1987 ± 0.0019 Å
• α: 90°
• β: 91.721 ± 0.004°
• γ: 90°
• Cell volume: 15357 ± 1.8 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0555
• Residual factor for significantly intense reflections: 0.0394
• Weighted residual factors for significantly intense reflections: 0.0777
• Weighted residual factors for all reflections included in the refinement: 0.0874
• Goodness-of-fit parameter for all reflections included in the refinement: 1.065
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No