Information card for entry 7710261

Structure parameters

• Chemical name: [Co(L1SO2)(phen)](SbF6)2
• Formula: C31.13 H33.96 Co F12 N6.43 O2.57 S Sb2
• Calculated formula: C31.132 H33.962 Co F12 N6.434 O2.566 S Sb2
• Title of publication: Probing the redox-conversion of Co(ii)-disulfide to Co(iii)-thiolate complexes: the effect of ligand-field strength
• Authors of publication: Marvelous, Christian; de Azevedo Santos, Lucas; Siegler, Maxime A.; Fonseca Guerra, Célia; Bouwman, Elisabeth
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 21.5627 ± 0.0005 Å
• b: 13.6523 ± 0.0004 Å
• c: 14.0315 ± 0.0004 Å
• α: 90°
• β: 103.059 ± 0.003°
• γ: 90°
• Cell volume: 4023.8 ± 0.2 ų
• Cell temperature: 110 ± 2 K
• Ambient diffraction temperature: 110 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0551
• Residual factor for significantly intense reflections: 0.0393
• Weighted residual factors for significantly intense reflections: 0.0924
• Weighted residual factors for all reflections included in the refinement: 0.102
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No