Information card for entry 7711535

Structure parameters

• Formula: C55 H54 Ag Cl3 O3 P4
• Calculated formula: C55 H54 Ag Cl3 O3 P4
• SMILES: [Ag]1([P](CP(c2ccccc2)(c2ccccc2)=C[P+](c2ccccc2)(c2ccccc2)C[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)Cl.ClCCl.O=C([O-])C.OC
• Title of publication: Cationic ligands between σ-donation and hydrogen-bridge-bond- stabilisation of ancillary ligands in coinage metal complexes with protonated carbodiphosphoranes
• Authors of publication: Maser, Leon; Vogt, Matthias; Langer, Robert
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 11.571 ± 0.002 Å
• b: 18.782 ± 0.004 Å
• c: 13.122 ± 0.003 Å
• α: 90°
• β: 114.91 ± 0.03°
• γ: 90°
• Cell volume: 2586.5 ± 1.1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.043
• Residual factor for significantly intense reflections: 0.0354
• Weighted residual factors for significantly intense reflections: 0.0732
• Weighted residual factors for all reflections included in the refinement: 0.0748
• Goodness-of-fit parameter for all reflections included in the refinement: 0.923
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No