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Information card for entry 7711903
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Coordinates | 7711903.cif |
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Original paper (by DOI) | HTML |
Chemical name | η2-{Bis(diphenylphosphanyl)ethyne}-bromido-carbonyl-hydrido{tris(3,4,5-trimethylpyrazolyl)borato}-tungsten(II) |
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Formula | C50 H60 B Br N6 O P2 W |
Calculated formula | C45 H48 B Br N6 O P2 W |
Title of publication | Tuning the potential of redox-active diphosphine ligands based on the alkyne complexes [Tp*W(CO)L{η<sup>2</sup>-C<sub>2</sub>(PPh<sub>2</sub>)<sub>2</sub>}]. |
Authors of publication | Ludwig, Stephan; Hamann, Friederike M.; Helmdach, Kai; Villinger, Alexander; Seidel, Wolfram W. |
Journal of publication | Dalton transactions (Cambridge, England : 2003) |
Year of publication | 2023 |
Journal volume | 52 |
Journal issue | 2 |
Pages of publication | 326 - 337 |
a | 13.1304 ± 0.0004 Å |
b | 19.4822 ± 0.0006 Å |
c | 19.7195 ± 0.0006 Å |
α | 90° |
β | 99.166 ± 0.001° |
γ | 90° |
Cell volume | 4980 ± 0.3 Å3 |
Cell temperature | 123 ± 2 K |
Ambient diffraction temperature | 123 ± 2 K |
Number of distinct elements | 8 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.0246 |
Residual factor for significantly intense reflections | 0.0189 |
Weighted residual factors for significantly intense reflections | 0.0416 |
Weighted residual factors for all reflections included in the refinement | 0.0434 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.079 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | Yes |
Has Fobs | No |
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The link is: https://www.crystallography.net/7711903.html
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