Information card for entry 7712341

Structure parameters

• Formula: C39 H60 B N8 O Si3 Y
• Calculated formula: C39 H60 B N8 O Si3 Y
• SMILES: [Y]12345(N([Si](C)(C)C)[Si](C)([CH]5=[C]2(N3[SiH2]c2ccccc2)Cc2ccccc2)C)([O]2CCCC2)[n]2n(c(cc2C)C)[BH](n2[n]1c(cc2C)C)n1[n]4c(cc1C)C
• Title of publication: Selective Si−C(sp3) Bond Cleavage of Silyl−Bridged Amido Alkyl Ligand in an Yttrium Complex
• Authors of publication: Cai, Jiamin; Zhang, Jie; Zhou, Xigeng
• Journal of publication: Dalton Transactions
• Year of publication: 2023
• a: 9.8288 ± 0.0006 Å
• b: 10.6314 ± 0.0006 Å
• c: 21.1115 ± 0.0012 Å
• α: 100.208 ± 0.002°
• β: 90.122 ± 0.002°
• γ: 95.118 ± 0.002°
• Cell volume: 2162.1 ± 0.2 ų
• Cell temperature: 172.99 K
• Ambient diffraction temperature: 172.99 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0632
• Residual factor for significantly intense reflections: 0.057
• Weighted residual factors for significantly intense reflections: 0.1785
• Weighted residual factors for all reflections included in the refinement: 0.1852
• Goodness-of-fit parameter for all reflections included in the refinement: 1.087
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.34138 Å
• Diffraction radiation type: GaKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No