Information card for entry 7712380

Structure parameters

• Formula: C55 H70 Au F6 N O4 P3 Rh S2
• Calculated formula: C55 H70 Au F6 N O4 P3 Rh S2
• SMILES: [Au]([Rh]1234([P](C)(C)C)([P](C)(C)C)[cH]5[cH]1[c]12[c]3([cH]45)cccc1)[P](c1c(cccc1c1c(cccc1C)C)c1c(cccc1C)C)(C1CCCC1)C1CCCC1.S(=O)([O-])(=NS(=O)(=O)C(F)(F)F)C(F)(F)F.c1ccccc1
• Title of publication: Polarized Au(I)/Rh(I) Bimetallic Pairs Cooperatively Trigger Ligand non-Innocence and Bond Activation
• Authors of publication: González Alférez, Macarena; Moreno, Juan J.; Maya, Celia; Campos, Jesús
• Journal of publication: Dalton Transactions
• Year of publication: 2023
• a: 14.1319 ± 0.0013 Å
• b: 17.4134 ± 0.0015 Å
• c: 23.475 ± 0.002 Å
• α: 85.692 ± 0.004°
• β: 88.744 ± 0.004°
• γ: 86.622 ± 0.004°
• Cell volume: 5749.6 ± 0.9 ų
• Cell temperature: 193 K
• Ambient diffraction temperature: 193 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.151
• Residual factor for significantly intense reflections: 0.0863
• Weighted residual factors for significantly intense reflections: 0.1661
• Weighted residual factors for all reflections included in the refinement: 0.1991
• Goodness-of-fit parameter for all reflections included in the refinement: 1.052
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No