Group 3 dialkyl complexes of a rigid monoanionic NNN-donor pincer ligand: synthesis, structures, unexpected reactivity with CPh<sub>3</sub><sup>+</sup>, and hydroamination catalysis.
Authors of publication
Vasanthakumar, Aathith; Gray, Novan A. G.; Franko, Christopher J.; Murphy, Maia C.; Emslie, David J. H.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2023
a
11.7271 ± 0.0006 Å
b
33.9737 ± 0.0017 Å
c
12.2113 ± 0.0006 Å
α
90°
β
106.235 ± 0.003°
γ
90°
Cell volume
4671.1 ± 0.4 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0656
Residual factor for significantly intense reflections
0.0437
Weighted residual factors for significantly intense reflections
0.0947
Weighted residual factors for all reflections included in the refinement
0.1014
Goodness-of-fit parameter for all reflections included in the refinement
