Information card for entry 7712897

Structure parameters

• Formula: C17 H19 Co O6
• Calculated formula: C17 H19 Co O6
• Title of publication: A mononuclear cobalt(III) carboxylate complex with a fully O-based coordination sphere: CoIII-O bond homolysis and controlled radical polymerisation from [Co(acac)2(O2CPh)]
• Authors of publication: Michelas, Maxime; Daran, Jean-Claude; Saquet, Alix; Fliedel, Christophe; Poli, Rinaldo
• Journal of publication: Dalton Transactions
• Year of publication: 2023
• a: 10.8167 ± 0.0009 Å
• b: 12.0499 ± 0.0011 Å
• c: 13.5182 ± 0.0011 Å
• α: 90°
• β: 103.533 ± 0.009°
• γ: 90°
• Cell volume: 1713 ± 0.3 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 4
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.2088
• Residual factor for significantly intense reflections: 0.1552
• Weighted residual factors for significantly intense reflections: 0.4498
• Weighted residual factors for all reflections included in the refinement: 0.5302
• Goodness-of-fit parameter for all reflections included in the refinement: 1.827
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No