Information card for entry 7713045

Structure parameters

• Formula: C26 H28 Au2 F34 N4 P4
• Calculated formula: C26 H28 Au2 F34 N4 P4
• SMILES: [Au](=C1N(C)C=CN1[P](F)(F)(C(F)(F)C(F)(F)F)(C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)F)=C1N([P](F)(F)(C(F)(F)C(F)(F)F)(C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)F)C=CN1C.[Au]([P](C)(C)C)[P](C)(C)C
• Title of publication: Anionic N-Heterocyclic Carbenes Featuring Weakly Coordinating Perfluoroalkylphosphorane Moieties
• Authors of publication: Zapf, Ludwig; Radius, Udo; Finze, Maik
• Journal of publication: Dalton Transactions
• Year of publication: 2023
• a: 11.504 ± 0.0002 Å
• b: 14.8392 ± 0.0003 Å
• c: 15.2026 ± 0.0003 Å
• α: 108.414 ± 0.002°
• β: 102.734 ± 0.002°
• γ: 110.562 ± 0.002°
• Cell volume: 2139.09 ± 0.1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100.01 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0317
• Residual factor for significantly intense reflections: 0.0253
• Weighted residual factors for significantly intense reflections: 0.0551
• Weighted residual factors for all reflections included in the refinement: 0.0567
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No