Information card for entry 7713464

Structure parameters

• Formula: C25 H28 Cl Ir N2 O
• Calculated formula: C25 H28 Cl Ir N2 O
• Title of publication: Half-Sandwich Iridium Complexes with Hydrazone Ligands: Preparation, Structure and Catalytic Synthesis of Cyanosilylethers under Air
• Authors of publication: Yao, Zi-Jian; Gao, Song; Liu, Zhen-Jiang; Luo, Yu-Zhou
• Journal of publication: Dalton Transactions
• Year of publication: 2023
• a: 8.612 ± 0.0003 Å
• b: 11.8772 ± 0.0004 Å
• c: 22.734 ± 0.0008 Å
• α: 90°
• β: 97.796 ± 0.001°
• γ: 90°
• Cell volume: 2303.89 ± 0.14 ų
• Cell temperature: 174 ± 2 K
• Ambient diffraction temperature: 174 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0305
• Residual factor for significantly intense reflections: 0.0293
• Weighted residual factors for significantly intense reflections: 0.0787
• Weighted residual factors for all reflections included in the refinement: 0.0797
• Goodness-of-fit parameter for all reflections included in the refinement: 1.078
• Diffraction radiation wavelength: 1.34138 Å
• Diffraction radiation type: GaKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No