Information card for entry 7714102

Structure parameters

• Formula: C59.4 H79.75 Cl4 F1.65 Ge2 N4 P2
• Calculated formula: C54 H73 Cl4 F Ge2 N4 P2
• Title of publication: Triphosphiranes as Phosphinidene-Transfer Agents – Synthesis of Regular and Chelating NHC Phosphinidene Adducts
• Authors of publication: Siewert, Jan-Erik; Schumann, André; Wellnitz, Tim; Dankert, Fabian; Hering-Junghans, Christian
• Journal of publication: Dalton Transactions
• Year of publication: 2023
• a: 9.6037 ± 0.0005 Å
• b: 16.1076 ± 0.0008 Å
• c: 22.4447 ± 0.001 Å
• α: 110.61 ± 0.003°
• β: 98.326 ± 0.003°
• γ: 93.649 ± 0.003°
• Cell volume: 3190.8 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0651
• Residual factor for significantly intense reflections: 0.0526
• Weighted residual factors for significantly intense reflections: 0.1399
• Weighted residual factors for all reflections included in the refinement: 0.1524
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No