Information card for entry 7714462

Structure parameters

• Chemical name: 1-MeCN
• Formula: C14 H3 F24 Ge N O4
• Calculated formula: C14 H3 F24 Ge N O4
• SMILES: [Ge]12(OC(C(O1)(C(F)(F)F)C(F)(F)F)(C(F)(F)F)C(F)(F)F)(OC(C(O2)(C(F)(F)F)C(F)(F)F)(C(F)(F)F)C(F)(F)F)[N]#CC
• Title of publication: A neutral germanium-centred hard and soft lewis superacid and its unique reactivity towards hydrosilanes.
• Authors of publication: Tschernuth, Florian S.; Kostenko, Arseni; Stigler, Sebastian; Gradenegger, Anna; Inoue, Shigeyoshi
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2023
• Journal volume: 53
• Journal issue: 1
• Pages of publication: 74 - 81
• a: 23.5238 ± 0.0015 Å
• b: 8.6067 ± 0.0005 Å
• c: 21.8982 ± 0.0013 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4433.6 ± 0.5 ų
• Cell temperature: 102 K
• Ambient diffraction temperature: 102 K
• Number of distinct elements: 6
• Space group number: 60
• Hermann-Mauguin space group symbol: P b c n
• Hall space group symbol: -P 2n 2ab
• Residual factor for all reflections: 0.0686
• Residual factor for significantly intense reflections: 0.0458
• Weighted residual factors for significantly intense reflections: 0.1171
• Weighted residual factors for all reflections included in the refinement: 0.1315
• Goodness-of-fit parameter for all reflections included in the refinement: 1.017
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No