Information card for entry 7714806

Structure parameters

• Formula: C30 H45 Cl F2 N4 Ni2 O7.25
• Calculated formula: C28 H40 F2 N4 Ni2 O7
• Title of publication: Tetracosanuclear nickel complexes as effective catalysts for cycloaddition of carbon dioxide with epoxides.
• Authors of publication: Liu, Guan-Lin; Wu, En-Hsu; Hung, Yu-Ching; Chou, Wei-Chi; Hung, Chia-Hsin; Lin, Chu-Chieh; Ko, Bao-Tsan
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2024
• Journal volume: 53
• Journal issue: 4
• Pages of publication: 1425 - 1429
• a: 12.1743 ± 0.0008 Å
• b: 17.2045 ± 0.0012 Å
• c: 18.9504 ± 0.0013 Å
• α: 107.87 ± 0.002°
• β: 107.105 ± 0.003°
• γ: 99.032 ± 0.002°
• Cell volume: 3474.7 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150.15 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0562
• Residual factor for significantly intense reflections: 0.0398
• Weighted residual factors for significantly intense reflections: 0.1071
• Weighted residual factors for all reflections included in the refinement: 0.12
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No