Information card for entry 7717663

Structure parameters

• Formula: C30 H46 O3 Si2 W
• Calculated formula: C30 H46 O3 Si2 W
• Title of publication: A hydrogen-bridged bis(silylene) complex as a platform for small molecule activation <i>via</i> adjacent metal-ligand cooperation.
• Authors of publication: Hashimoto, Hisako; Matsuo, Satomi; Odagiri, Yuto; Tobita, Hiromi
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2025
• Journal volume: 54
• Journal issue: 3
• Pages of publication: 915 - 919
• a: 13.6063 ± 0.0003 Å
• b: 16.0363 ± 0.0004 Å
• c: 14.7843 ± 0.0003 Å
• α: 90°
• β: 104.088 ± 0.0006°
• γ: 90°
• Cell volume: 3128.83 ± 0.12 ų
• Cell temperature: 140 ± 2 K
• Ambient diffraction temperature: 140 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0453
• Residual factor for significantly intense reflections: 0.0376
• Weighted residual factors for significantly intense reflections: 0.0797
• Weighted residual factors for all reflections included in the refinement: 0.0825
• Goodness-of-fit parameter for all reflections included in the refinement: 1.151
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No