Information card for entry 8000032

Structure parameters

• Common name: hexakis{bis(L-prolinato)cobalt(II)}lanthanum(III) tetramethylammonium perchlorate
• Formula: C64 H108 Cl4 Co6 La N13 O40
• Calculated formula: C64 H108 Cl4 Co6 La N13 O40
• Title of publication: Changing Mixed-valence State of Hexacobalt Cluster by Substituting Central Metal Ion and by Electrochemical Reduction ‒ Different Mixed-valence States of [M{Co(prolinato)2}6]4+ (M =Ba2+ and La3+)
• Authors of publication: Takashi Komiyama; Satoshi Igarashi; Yoshimasa Hoshino; Yasuhiko Yukawa
• Journal of publication: Chemistry Letters
• Year of publication: 2005
• Journal volume: 34
• Journal issue: 3
• Pages of publication: 300
• a: 21.338 ± 0.001 Å
• b: 21.338 ± 0.001 Å
• c: 21.338 ± 0.001 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 9714.8 ± 0.8 ų
• Cell temperature: 296.2 K
• Ambient diffraction temperature: 296.2 K
• Number of distinct elements: 7
• Space group number: 196
• Hermann-Mauguin space group symbol: F 2 3
• Hall space group symbol: F 2 2 3
• Residual factor for significantly intense reflections: 0.043
• Weighted residual factors for all reflections included in the refinement: 0.0572
• Goodness-of-fit parameter for all reflections included in the refinement: 0.921
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No