Information card for entry 8100083

Structure parameters

• Formula: C56 H52 Cl6 Mo N4 P2
• Calculated formula: C28 H26 Cl3 Mo0.5 N2 P
• SMILES: [Mo](Cl)(Cl)(Cl)(Cl)(Cl)[Cl-].[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.N#CC.N#CC.N#CC.N#CC
• Title of publication: Crystal structures of acetonitrile solvates of bis(tetraphenylphosphonium) tetrachlorooxovanadate(IV), hexachlorostannate(IV) and -molybdate (IV), [P(C~6~H~5~)~4~]~2~[VOCl~4~] · 4CH~3~CN, [P(C~6~H~5~)~4~]~2~ [MCl~6~] · 4CH~3~CN (M = Sn, Mo)
• Authors of publication: Rabe, Susanne; Bubenheim, Winfried; Müller, Ulrich
• Journal of publication: Zeitschrift für Kristallographie - New Crystal Structures
• Year of publication: 2004
• Journal volume: 219
• Journal issue: 2
• Pages of publication: 101 - 105
• a: 9.505 ± 0.003 Å
• b: 19.624 ± 0.002 Å
• c: 14.759 ± 0.002 Å
• α: 90°
• β: 98.72 ± 0.02°
• γ: 90°
• Cell volume: 2721.1 ± 1 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No