Information card for entry 8100259

Structure parameters

• Formula: C91 H89 Cl28 O12 P6 Ru2
• Calculated formula: C91 H89 Cl28 O12 P6 Ru2
• SMILES: [Ru]1234([Cl][Ru]56([Cl]1)([Cl]2)[P](OCC(CO[P]5(c1ccccc1)c1ccccc1)(CO[P]6(c1ccccc1)c1ccccc1)C)(c1ccccc1)c1ccccc1)[P](OCC(CO[P]3(c1ccccc1)c1ccccc1)(CO[P]4(c1ccccc1)c1ccccc1)C)(c1ccccc1)c1ccccc1.[Cl-].C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.O.O.O.O.O.OC
• Title of publication: Crystal structure of dichloro-[1-diphenylphosphinyloxy-2,2-bis(diphenyl- phosphinyloxymethyl)propane]ruthenium(II) solvate, C~82~H~78~Cl~4~O~6~P~6~Ru~2~ · 8CHCl~3~ · CH~3~OH · 5H~2~O, a novel tridentate phosphinite-Ru complex used as a model of heterogenized oxidation catalyst
• Authors of publication: Tinant, B.; Duliere, E.; Devillers, M.; Marchand-Brynaert, J.
• Journal of publication: Zeitschrift für Kristallographie - New Crystal Structures
• Year of publication: 2003
• Journal volume: 218
• Journal issue: 1
• Pages of publication: 59 - 62
• a: 21.984 ± 0.007 Å
• b: 25.643 ± 0.008 Å
• c: 23.102 ± 0.007 Å
• α: 90°
• β: 114.54 ± 0.03°
• γ: 90°
• Cell volume: 11847 ± 6 ų
• Cell temperature: 110 ± 2 K
• Ambient diffraction temperature: 110 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/a 1
• Hall space group symbol: -P 2yab
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No