Information card for entry 8102179

Structure parameters

• Chemical name: 1-(2-(dicyclohexylphosphinophenyl)pyrol-2-dicyclohexylphosphino-rhodium(I) norborna-2,5-diene tetrafluoroborate tetrahydrofuran hemisolvate
• Formula: C43 H63 B F4 N O0.5 P2 Rh
• Calculated formula: C43 H63 B F4 N O0.5 P2 Rh
• Title of publication: Crystal structures of 1-(2-(dicyclohexylphosphinophenyl)-pyrol-2- dicyclohexylphosphino-rhodium(I) norborna-2,5-diene tetrafluoroborate tetrahydrofuran hemisolvate, [Rh(C~34~H~51~NP~2~)(C~7~H~8~)][BF~4~] · 0.5C~4~H~8~O, and 1-(2-(dicyclohexylphosphinophenyl)-pyrol-2-dicyclohexyl- phosphino-rhodium(I) (Z,Z)-cycloocta-1,5-diene tetrafluoroborate, [Rh(C~34~H~51~NP~2~)(C~8~H~12~)][BF~4~]
• Authors of publication: Jackstell, Ralf; Dai, Zhenya; Schmidt, Thomas; Heller, Detlef; Drexler, Hans-Joachim
• Journal of publication: Zeitschrift für Kristallographie - New Crystal Structures
• Year of publication: 2007
• Journal volume: 222
• Journal issue: 4
• Pages of publication: 458 - 462
• a: 10.341 ± 0.002 Å
• b: 16.063 ± 0.003 Å
• c: 27.425 ± 0.005 Å
• α: 90°
• β: 98.76 ± 0.03°
• γ: 90°
• Cell volume: 4502.4 ± 1.5 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1007
• Residual factor for significantly intense reflections: 0.0596
• Weighted residual factors for significantly intense reflections: 0.1336
• Weighted residual factors for all reflections included in the refinement: 0.1433
• Goodness-of-fit parameter for all reflections included in the refinement: 0.886
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No