Information card for entry 1549758

Structure parameters

• Formula: C50 H58 Ag Al2 Br2 Cl4 F55 O6 Si2
• Calculated formula: C50 H58 Ag Al2 Br2 Cl4 F55 O6 Si2
• SMILES: O(C(C(F)(F)F)(C(F)(F)F)C(F)(F)F)[Al](OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)(OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)[F][Al](OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)(OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F.[Ag]([Cl]CCl)([Cl]CCl)([Br][Si](C(C)(C)C)(C(C)(C)C)C(C)(C)C)[Br][Si](C(C)(C)C)(C(C)(C)C)C(C)(C)C
• Title of publication: Facile and systematic access to the least-coordinating WCA [(R^FO)₃Al-F-Al(OR^F)₃]^- and its more Lewis-basic brother [F-Al(OR^F)₃]^- (R^F = C(CF₃)₃).
• Authors of publication: Martens, Arthur; Weis, Philippe; Krummer, Michael Christian; Kreuzer, Marvin; Meierhöfer, Andreas; Meier, Stefan C.; Bohnenberger, Jan; Scherer, Harald; Riddlestone, Ian; Krossing, Ingo
• Journal of publication: Chemical science
• Year of publication: 2018
• Journal volume: 9
• Journal issue: 35
• Pages of publication: 7058 - 7068
• a: 15.476 ± 0.0018 Å
• b: 16.615 ± 0.002 Å
• c: 18.2967 ± 0.0019 Å
• α: 89.488 ± 0.004°
• β: 67.742 ± 0.004°
• γ: 70.537 ± 0.004°
• Cell volume: 4068.1 ± 0.8 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0327
• Residual factor for significantly intense reflections: 0.0272
• Weighted residual factors for significantly intense reflections: 0.0665
• Weighted residual factors for all reflections included in the refinement: 0.0693
• Goodness-of-fit parameter for all reflections included in the refinement: 1.029
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No