Information card for entry 1573732

Structure parameters

• Formula: C79 H80 B5 F24 N5 O2 Sn
• Calculated formula: C78 H69 B F24 N4 O2 Sn
• Title of publication: CO₂ hydrosilylation catalyzed by an N-heterocyclic carbene (NHC)-stabilized stannyliumylidene.
• Authors of publication: Niu, Dechuang; Kostenko, Arseni; Kelly, John A.; Sarkar, Debotra; Xu, Huihui; Inoue, Shigeyoshi
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 9
• Pages of publication: 4014 - 4022
• a: 15.245 ± 0.0013 Å
• b: 17.2704 ± 0.0013 Å
• c: 17.6243 ± 0.0014 Å
• α: 92.495 ± 0.003°
• β: 102.397 ± 0.003°
• γ: 112.807 ± 0.002°
• Cell volume: 4136.1 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0457
• Residual factor for significantly intense reflections: 0.0418
• Weighted residual factors for significantly intense reflections: 0.1026
• Weighted residual factors for all reflections included in the refinement: 0.1061
• Goodness-of-fit parameter for all reflections included in the refinement: 1.067
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No