Information card for entry 1573733

Structure parameters

• Formula: C70.01 H61 B F24 N4 Sn
• Calculated formula: C70 H61 B F24 N4 Sn
• Title of publication: CO₂ hydrosilylation catalyzed by an N-heterocyclic carbene (NHC)-stabilized stannyliumylidene.
• Authors of publication: Niu, Dechuang; Kostenko, Arseni; Kelly, John A.; Sarkar, Debotra; Xu, Huihui; Inoue, Shigeyoshi
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 9
• Pages of publication: 4014 - 4022
• a: 13.4232 ± 0.0004 Å
• b: 17.0569 ± 0.0006 Å
• c: 18.5469 ± 0.0007 Å
• α: 102.535 ± 0.003°
• β: 101.839 ± 0.003°
• γ: 109.969 ± 0.003°
• Cell volume: 3711.1 ± 0.3 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0649
• Residual factor for significantly intense reflections: 0.0484
• Weighted residual factors for significantly intense reflections: 0.1198
• Weighted residual factors for all reflections included in the refinement: 0.1323
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No