Information card for entry 1574299

Structure parameters

• Formula: C36 H38 N3 P S2 Si
• Calculated formula: C36 H38 N3 P S2 Si
• SMILES: [Si]1(C(=P(c2ccccc2)(c2ccccc2)c2ccccc2)C#N)([N](=C(N1C(C)(C)C)c1ccccc1)C(C)(C)C)C(=S)[S-]
• Title of publication: Base-stabilized acyclic amino(ylidyl)silylenes: electron-rich donors for the stabilization of silicon-element multiple bonds
• Authors of publication: Krischer, Felix; Mayer, Stephan; Hensle, Lennart; Knyszek, Daniel; Darmandeh, Heidar; Gessner, Viktoria H.
• Journal of publication: Chemical Science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 19
• Pages of publication: 8346 - 8356
• a: 14.8143 ± 0.0001 Å
• b: 14.4078 ± 0.0001 Å
• c: 17.4032 ± 0.0002 Å
• α: 90°
• β: 114.35 ± 0.001°
• γ: 90°
• Cell volume: 3384.13 ± 0.06 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0352
• Residual factor for significantly intense reflections: 0.0326
• Weighted residual factors for significantly intense reflections: 0.0893
• Weighted residual factors for all reflections included in the refinement: 0.0913
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No