Information card for entry 1574492

Structure parameters

• Formula: C18 H23 F O Si
• Calculated formula: C18 H23 F O Si
• SMILES: [Si](OC(C)(C)C)(c1c(F)c(ccc1)c1ccccc1)(C)C
• Title of publication: Catalytic alkoxysilylation of C–H bonds with tert-butyl-substituted alkoxysilyldiazenes
• Authors of publication: Saadi, Lamine; Valade, Loïc; Chauvier, Clément
• Journal of publication: Chemical Science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 22
• Pages of publication: 9794 - 9801
• a: 6.8159 ± 0.0008 Å
• b: 10.7178 ± 0.0011 Å
• c: 12.2818 ± 0.0013 Å
• α: 78.849 ± 0.004°
• β: 85.474 ± 0.004°
• γ: 86.837 ± 0.004°
• Cell volume: 876.79 ± 0.17 ų
• Cell temperature: 200 ± 1 K
• Ambient diffraction temperature: 200 ± 1 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1321
• Residual factor for significantly intense reflections: 0.0765
• Weighted residual factors for significantly intense reflections: 0.1256
• Weighted residual factors for all reflections included in the refinement: 0.1436
• Goodness-of-fit parameter for all reflections included in the refinement: 1.033
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No