Information card for entry 1574669

Structure parameters

• Formula: C44 H68 B10 Bi I N4 Si2
• Calculated formula: C32 H56 B10 Bi I N4 Si2
• Title of publication: Isolable monoatomic monovalent bismuth complexes with a redox non-innocent bis-silylenyl carborane ligand
• Authors of publication: Xu, Jian; Yao, Shenglai; Postils, Verònica; Matito, Eduard; Lorent, Christian; Driess, Matthias
• Journal of publication: Chemical Science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 24
• Pages of publication: 10826 - 10832
• a: 13.6332 ± 0.0002 Å
• b: 18.0507 ± 0.0003 Å
• c: 21.0915 ± 0.0003 Å
• α: 90°
• β: 95.283 ± 0.001°
• γ: 90°
• Cell volume: 5168.33 ± 0.14 ų
• Cell temperature: 110.07 ± 0.12 K
• Ambient diffraction temperature: 110.07 ± 0.12 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0345
• Residual factor for significantly intense reflections: 0.0319
• Weighted residual factors for significantly intense reflections: 0.08
• Weighted residual factors for all reflections included in the refinement: 0.0818
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No