Information card for entry 1574670

Structure parameters

• Formula: C88 H160 B20 Bi2 K2 N8 O6 Si4
• Calculated formula: C88 H160 B20 Bi2 K2 N8 O6 Si4
• Title of publication: Isolable monoatomic monovalent bismuth complexes with a redox non-innocent bis-silylenyl carborane ligand
• Authors of publication: Xu, Jian; Yao, Shenglai; Postils, Verònica; Matito, Eduard; Lorent, Christian; Driess, Matthias
• Journal of publication: Chemical Science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 24
• Pages of publication: 10826 - 10832
• a: 10.0567 ± 0.0004 Å
• b: 14.8404 ± 0.0006 Å
• c: 19.9981 ± 0.0008 Å
• α: 70.8 ± 0.004°
• β: 86.199 ± 0.003°
• γ: 84.365 ± 0.003°
• Cell volume: 2803.2 ± 0.2 ų
• Cell temperature: 111.5 ± 0.6 K
• Ambient diffraction temperature: 111.5 ± 0.6 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0526
• Residual factor for significantly intense reflections: 0.0448
• Weighted residual factors for significantly intense reflections: 0.1134
• Weighted residual factors for all reflections included in the refinement: 0.1207
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No