Information card for entry 1574673

Structure parameters

• Formula: C36 H61 B10 Bi Cl2 F6 N4 O6 S2 Si2
• Calculated formula: C36 H61 B10 Bi Cl2 F6 N4 O6 S2 Si2
• Title of publication: Isolable monoatomic monovalent bismuth complexes with a redox non-innocent bis-silylenyl carborane ligand
• Authors of publication: Xu, Jian; Yao, Shenglai; Postils, Verònica; Matito, Eduard; Lorent, Christian; Driess, Matthias
• Journal of publication: Chemical Science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 24
• Pages of publication: 10826 - 10832
• a: 16.1469 ± 0.0004 Å
• b: 18.081 ± 0.0003 Å
• c: 18.3593 ± 0.0004 Å
• α: 90°
• β: 98.144 ± 0.002°
• γ: 90°
• Cell volume: 5306 ± 0.2 ų
• Cell temperature: 111.3 ± 0.6 K
• Ambient diffraction temperature: 111.15 K
• Number of distinct elements: 10
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0799
• Residual factor for significantly intense reflections: 0.062
• Weighted residual factors for significantly intense reflections: 0.1785
• Weighted residual factors for all reflections included in the refinement: 0.2149
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No