Information card for entry 1575934

Structure parameters

• Formula: C93.5 H79 Ce K2 O5 Si5
• Calculated formula: C90 H75 Ce K2 O5 Si5
• Title of publication: Accessing homoleptic neutral and anionic five-coordinate Pr(iv) siloxide complexes.
• Authors of publication: Pandey, Pragati; Keener, Megan; Rajeshkumar, Thayalan; Scopelliti, Rosario; Sienkiewicz, Andrzej; Zivkovic, Ivica; Maron, Laurent; Mazzanti, Marinella
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 44
• Pages of publication: 21056 - 21067
• a: 13.6841 ± 0.0009 Å
• b: 23.2083 ± 0.0015 Å
• c: 27.761 ± 0.002 Å
• α: 109.761 ± 0.006°
• β: 95.331 ± 0.006°
• γ: 90.676 ± 0.005°
• Cell volume: 8252.6 ± 1 ų
• Cell temperature: 200 ± 0.11 K
• Ambient diffraction temperature: 200 ± 0.11 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.234
• Residual factor for significantly intense reflections: 0.0966
• Weighted residual factors for significantly intense reflections: 0.1855
• Weighted residual factors for all reflections included in the refinement: 0.274
• Goodness-of-fit parameter for all reflections included in the refinement: 0.954
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No