Information card for entry 1575935

Structure parameters

• Formula: C104 H91 Cs O5 Pr Si5
• Calculated formula: C104 H91 Cs O5 Pr Si5
• Title of publication: Accessing homoleptic neutral and anionic five-coordinate Pr(iv) siloxide complexes.
• Authors of publication: Pandey, Pragati; Keener, Megan; Rajeshkumar, Thayalan; Scopelliti, Rosario; Sienkiewicz, Andrzej; Zivkovic, Ivica; Maron, Laurent; Mazzanti, Marinella
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 44
• Pages of publication: 21056 - 21067
• a: 13.7546 ± 0.0018 Å
• b: 24.859 ± 0.003 Å
• c: 14.1649 ± 0.0018 Å
• α: 90°
• β: 113.942 ± 0.016°
• γ: 90°
• Cell volume: 4426.6 ± 1.1 ų
• Cell temperature: 140 ± 0.1 K
• Ambient diffraction temperature: 140 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.1165
• Residual factor for significantly intense reflections: 0.0714
• Weighted residual factors for significantly intense reflections: 0.1436
• Weighted residual factors for all reflections included in the refinement: 0.1784
• Goodness-of-fit parameter for all reflections included in the refinement: 0.9344
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No